Calling IsNullOrWhiteSpace on an instance looks even more counter-intuitive to me, though – it wouldn't work on null if it were a real instance method.
It works because it's an extension method, but aren't extension methods supposed to make things nice and consistent by making it look as if you're calling an instance method?
Since this would be completely broken if it were an instance method, the reader might be surprised at first until they realize it's an extension method. So all I'm saying is that it's no less "counter-intuitive" than the normal string.IsNullOrWhiteSpace.