I'm trying to push for that WordPress ticket, but it's unlikely that we'll get any significant traction for a while. The database class in WP (apart from being fairly horrible) is a huge component to make major changes to like that, and we have to consider backwards compatibility.
Here's hoping it gets merged in the next 5 major releases. I'm not holding my breath.
I would say that people who develop on XP are even fewer than those who deploy on XP. It's a 12 year old OS -- surely they have moved to Vista, 7 or 8 by now.