I‘m a big fan of the four day workweek idea, but let’s not kid ourselves. 5 days are 5 days. I work 10h days usually and I just wouldn’t be able to fit all that work into 4 days.
I don't think human production is linear. There's definitely an optimal point, and it probably varies from person to person. I think, actually, past that point your productivity declines rapidly.
I would not be surprised at all if working 70 hours a week yields more productivity than 80, which yields more than 100.