“Ubuntu 7.10 is the first version of Ubuntu that ships with Compiz Fusion enabled by default on supported hardware. Compiz Fusion, which combines Compiz with certain components developed by the Beryl community, is a compositing window manager that adds a wide range of visual effects to Ubuntu's desktop environment. The default settings for Compiz enable basic effects—like window shadows and fading menus—that are subtle and unobtrusive. For more elaborate Compiz features, like wobbling windows, users can select the Extra option on the Visual Effects tab of the Appearance Preferences dialog.”
Yeah, I worked on that but I didn't think that would count since it was a distro, not a desktop environment. In that case Novell shipped compiz in 2006 so even earlier.
“Ubuntu 7.10 is the first version of Ubuntu that ships with Compiz Fusion enabled by default on supported hardware. Compiz Fusion, which combines Compiz with certain components developed by the Beryl community, is a compositing window manager that adds a wide range of visual effects to Ubuntu's desktop environment. The default settings for Compiz enable basic effects—like window shadows and fading menus—that are subtle and unobtrusive. For more elaborate Compiz features, like wobbling windows, users can select the Extra option on the Visual Effects tab of the Appearance Preferences dialog.”