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What do you mean by quantum effects? Tunneling?

If so, that's too restrictive. The interaction between two He atoms needs QM (dispersion forces). Heck, even two water molecules interacting is a QM even if you decide to classify the polar attraction as purely classical. You'd still be omitting a lot of the interaction energy.

I see no way I can simulate catalyzed (enzyme) breaking of a chemical bond without:

1. Direct or indirect use of at least DFT

2. An empirical solution (curve fitting to data)




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