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Will any crap we put into graphene increase its electrocatalytic effect? (2020) (acs.org)
145 points by stereoabuse on April 1, 2024 | hide | past | favorite | 55 comments


The paper did not answer the question in the title, since it used only one kind of crap. A broader study is called for.


Using @georgeburdell suggestion below of: https://pubs.acs.org/doi/10.1021/nn202625c we need an extensive study of crap grown on crap. 2x2, deuce on deuce. Bull, horse, chicken, swine, goat, sheep, sewer trout. Patty, nugget, loaf, steamer, log, and gravy configurations also need to be explored. Possibly also naturally sourced, like swimming pools, and the River Thames.


The age deucine has begun!


I guess they were trying for an IgNobel Prize? However, they don't report anything on the stability of the catalyst under reaction conditions, that is how many reaction cycles it goes through before losing catalytic effect.

If they don't report the lifetime, it's usually because the lifetime is crap, and all they have is a laboratory curiousity - which might, with futher diligent effort (and please, another research grant!), become industrially useful... maybe.


There isn't any difference between the guano graphene and the non-guano graphene in terms of structure -- look at figures 1 and 2. Figure 2A is clearly 4 of the same spectra because thermal exfoliation in the presence of guano doesn't create a materially different graphene than not in the presence of guano.

The rest of the paper is poking fun at all of the referenced papers that just have inconsistent electrochemical experimental setups that produce apparently increased electrocatalytic effects.


> We demonstrate in the following text the meaninglessness of the never-ending co-doping of graphene. We decided to follow the hyperbole of ever multiplying dopants; however, instead of using expensive and toxic chemicals such as ammonia, fluorine, chlorine, boranes, etc., we took a page from the pre-Haber−Bosch era and sought natural materials for the fertilization of graphene and used guano as a dopant.

What a wonderfully bat-shit paper.

> In summary, we demonstrated that bird dropping-treated graphenes indeed make graphene more electrocatalytic than nondoped graphene.

Oh, never mind, just bird-shit, dang.


Reminds me of the salmon study https://www.scientificamerican.com/blog/scicurious-brain/ign...

> the salmon was shown images of people in social situations, either socially inclusive situations or socially exclusive situations. The salmon was asked to respond, saying how the person in the situation must be feeling. The salmon, as far as I can tell from the paper, did not comply with instructions.


That’s a fabulous one. Thanks for sharing.


- "...societal impact not only in clean energy production and a cleaner environment but also on rural economies as guano once again becomes a valuable and highly sought-after product."

Apropos of nothing, the Guano Islands Act of 1856 is still, apparently, standing US law [0]. This research is an exciting opportunity for any who'd like to serve as mercenary privateers under the flag of the United States, while advancing science.

[0] https://en.wikipedia.org/wiki/Guano_Islands_Act


That was an interesting read only topped by the wild ride that was the linked article on "New Atlantis": https://en.wikipedia.org/wiki/New_Atlantis_(micronation)

> New Atlantis was a micronation formed by Leicester Hemingway, the brother of Ernest Hemingway. The "island", a 240 sq ft (22 m²) bamboo raft off the coast of Jamaica, was established as a constitutional republic on July 4, 1964.


My grandfather somehow assisted Hemingway in setting up New Atlantis and the documents declaring him and my grandmother Sir and Lady hang proudly in my living room. As far as I know my family is the sole remaining royal line of New Atlantis. Hilarious that this keeps coming up.


Say if you wanted to issue passports for New Atlantis, how do you go about doing that, is there some passport production machine that is purchasable off the shelf?


I can't say this has topic has come up in any recent New Atlantean Royal Council meetings but we would welcome you to make a presentation on the matter.


I literally lol'd... part of me wishes you'd go all in and claim the throne, create a website, issue royal decrees, etc. while you're at it


you could print a passport however you like, but that doesn't mean any other country will recognize it and allow you entry.


Solid Neal Stephenson subplot material


I can imagine a SF story where the act is applied to an abandoned, but still bird infested, space colony.


I now want a Star Wars story that involves a harvesting mynock guano from various astroids, perhaps with a crime lord.

"You think you can come here and disrespect me, by stealing MY shit?"


Are there any unclaimed islands left?

Sadly this wouldn’t apply to new islands since it takes a long time for bats to establish themselves.


My family actually claimed Howland island back in the early days of the guano act (they pivoted from clipper shipyards to guano shityards when international trade collapsed at the beginning of the civil war) [1]. I’d love to go there and, you know, live out my dreams, but WOW is transportation an issue. That place is FAR away.

Also, check out the super secret spy base on the west side of the island, loosely hidden by google maps treachery. What’s happening there?? [2]

[1] http://christophersetterlund.blogspot.com/2020/05/in-their-f...

[2] https://maps.app.goo.gl/Ly8W9M2fqdap7Mzc7?g_st=ic


Better hurry. At only 6m above sea level at its highest point, it may sink below the waves before long.


True that. But the whole potential is leveraging that huge dormant volcano under the water.


Villain lair!


> before long

Specifically, 1600 years at current rate.

(I have a personal bugbear about people worrying about sea level rise)


There are different sorts of rise to worry about.

There's "everything is always underwater" rise, whichbis 1600 years off. Then there's "average highwater mark during a storm at high tide", which will exceed those 6m a lot sooner and is the point at which the island ceases to become at all inhabitable.


[flagged]


I was actually worried for a second, then checked my last 10 comments and realized this is just the equivalent of "well your face is ugly" playground style insults, but for adults. Got me for a second though.


[flagged]


That's a lotta yapping to explain a playground insult


You can’t ignore that the variance and the sea level increases with climate change, especially at only 6m above.


And an island is, for practical purposes, gone well before its very highest point is below local mean sea level.


Not wanting to ruin a good joke, is this because imperfections in the alignment of otherwise pure substances provide opportunistic "holes" in structure for things like van der waals forces to work their magic?

I am reminded of the "you can develop photos with a banana and a spoon" (not really) stories, which underline the fundamentals of what photographic development is: a chemistry story which is not about the substances as much as about how base and acids combine. The photoreactive chemicals are highly specific, but the process of fixing them, and binding visible molecules to them or not, is more general.

Maybe the role of "contaminants" in graphine is similar? Not what it is, but what it DOES.


Related: graphene grown from crap

https://pubs.acs.org/doi/10.1021/nn202625c


Love the title!


Czechs trying to be funny...


Funniness check passed!


I don't. Science already has a credibility problem, and click-baity titles only make it worse.


Cannot be clickbaity if the title precisely explains what the paper is about.

The problem with science dissemination is not that it's too accessible but rather the polar opposite: even experts find reading some (many? Most?) papers truly dreadful because of the terse and dryness but one does it for the knowledge; on the other hand everyone else absolutely needs to rely on "science popularisers" to even half-understand half of what a paper is about. And that's the problem: the general scientific understanding is as good as the scientific rigor of the most understandable/entertaining science populariser out there.

To clarify: if person A is extremely diligent and precise but not too enjoyable to watch, they will get X views and maybe a limited (but positive) impact, on the other hand person B is not very diligent, cuts corners or even outright lies but is very easy and fun to watch, they reach N more people than person A, having an absolute huge (albeit negative) impact.

If the authors had a way to write both for experts and, somehow, have control on how that knowledge is available to the rest, the delta between the two methods of dissemination would be minimal (or at least controlled).


The title appears to work in the context of ACS Nano. Has 200+ citations, and cited by several other 200+ papers. Maybe double the average ACS Nano citations of 87 (Exaly says 1.5 million citations on 17,200 papers https://exaly.com/journal/12906/acs-nano) If other authors found it click baity, they found it click bait in a way that deserved inclusion in their own work above the norm of ACS Nano.


Do you think this paper would be on HN if it had a regular kind of title?

At this point, there are more comments about the title than about its contents.


Yes it would have. And the problem with science dissemination isn't click-baity titles, it's a combination of poorly executed science (hence the reproducibility and retraction crisis in many field), the abject, shameless hyperbole spewed by PR departments, and a lack of genuine scientific education


Would feces-doped graphene have gathered attention on HN? I dare say "yes"!


That is actually a humorous title.

Note that the title accurately describes what the article is about. As opposed to clickbait. Clickbait would have been "You would never believe what we put into graphene!".


That or "STOP putting THIS into Graphene now!!!"


plzzz like & subscribe *-*


If the paper is accurate, it's actilly making fun of all the serious-sounding papers adding whatever to graphene and publishing it as noteworthy results. After reading way more papers that I wish I had to, I can say I would prefer if all paper titles were this accessible and honest.


And there we got the problem, a papers title not sounding serious doesn't mean it isn't — and more importantly: the opposite is true as well.

The credibility problems science has is because instead of replicating the contents of a paper people have seveloped and over-reliance on other peripheral metrics like which papers it has been published in, p-values and such. Relying on the seriousness of titles is just another of those distractions.


Has the word click-bait lost all its meaning now


No. It now means 'content that offends my refined sensibilities'.

(But I'm with you, words matter, and I loved your comment).


As opposed to inscrutable two-line titles full of the field’s buzzwords on top of papers that you have to parse for hours to realize the idea and results could have been written in one sentence?

Maybe I’ve read too many applied machine learning papers. As long as the funny title isn’t dishonest, I’m all for it.


Actually, “clickbait” doesn’t really apply here, the paper supports the title.


They tested bird crap, but not other sorts if crap. And which birds? Does species matter?


On the other hand, the sanitized titles of scientific discourse can mask uncredibility and obscure the actual core thrust of a piece.


I adore that I live in a time where scientific articles have headlines with the word "crap".


I’ve heard it said that journal article titles tend to be less entertaining and whimsical than they used to be (perhaps due to increased pressure to conform to a standard style?). I’m glad to see a counterexample here though!


I feel like these authors read a lot of Derek Lowe. The style of humor seems very similar.


With text that continues with serious consideration of guano-doped graphene... Graphine chemistry has a meme!




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