Most of the US ones now are synced. I haven't tried out other countries. Initially, there were ~130 that I tried and got a 404 on all of them for the latest pacman. When I tried again a about half an hour ago, only ~50 of the US mirrors returned a 404
The 1 Gbit/s uplink for the Tier 0 mirror has been fully saturated for almost 4-5 hours now and I expect servers to be syncing for rest of the day really.
I would just go to https://archlinux.org/mirrorlist and generate your mirrorlist there. I've heard from others that reflector isn't detected newly synced mirrors at the moment.