A typical locomotive at 1 mph has more momentum than a Ford F-150 at 45 mph, but the latter is far more likely to kill you in collision so it doesn’t look like it is momentum that kills.
Doubling the mass of the car assuming everything else (crumple zones etc.) stays the same - doubles the acceleration experienced by the pedestrian.
X_p0 = X of the pedestrian before collision
X_c0 = X of the car before collision
X_p1 = X of the pedestrian after the collision
X_c1 = X of the car after the collision
m_ = mass
v_ = velocity
a_ = acceleration
t = time
//conservation of momentum:
m_p * v_p0 + m_c * v_c0 = m_p * v_p1 + m_c * v_c1
m_p * (v_p0 - v_p1) = m_c * (v_c1 - v_c0)
v_p1 - v_p0 = m_c * (v_c0 - v_c1) / m_p
// a = delta v / t
a = (v_p1 - v_p0)/t = m_c * (v_c0 - v_c1) / (m_p * t)