I recently found out Lex Fridman's podcast and I thoroughly enjoy it. Episodes I listened to are Jack Barsky, Stephen Kotkin, and currently the one with Neal Stephenson. He interviews a broad spectrum of people, about a myriad of topics. I skipped the CEOs though some here may find interview with Zuck or Elon interesting.
The interview with Zuck was really disappointing, he got a lot of flack for his mellow interviews of contentious persons and he's been trying to prod a little deeper on them since then. I think he's great at interviewing interesting people, but Zuck is just a PHP developer with good business accumen, there's not much interesting going on there.
Lex Friedman is imo the best podcast out there, but if he's got an interview with someone you dislike, I'd skip it because he'll not press on where you think he needs to press on to get to the heart of it.
