I’m not sure I understand the question. Are you implying that there are no other reasons to work for a startup, other than exposing yourself to risk? Might I suggest rock climbing or skydiving instead of startups?
The economic case for working at a startup is the risk. High risk of failure but a chance at a big payoff. He's probably saying that it's already accepted that that risk is there if you work for a startup.
I think the point is that for most employees, there is no chance of a "big payoff" (where "big" = 10X what you'd have made at an established company paying market wages).
In theory I own 1% of a startup worth $10m, but that will likely get diluted further and come to nothing. Even if it doesn't, I could have easily made an extra $100,000 over 3 or 4 years by just getting higher paying jobs at a regular company. And 1% is very high for employees, most of whom have a lot less equity.
The point is unless the startup becomes bigger than Google, most employees will lose out financially vs. working for a BigCorp.