The most important difference is that kolibrios is a team effort, and open source.
Menuetos abandoned its 32bit version (the one that was open) to focus on 64bit, which is not, and even has a clause in the license that prohibits disassembly.
Regardless of being closed source, I'm going to guess that it would still be highly educational to learn Assembly programming on a system that makes it a first class citizen where you just boot into the OS that already is entirely built around ASM. For really simple stuff, a simple microcontroller might be better, but I'm sure some folks are more interested in building desktop apps.