I recently wrote a brainfuck compiler using Rust [0], but I targeted x86-64 asm directly. I implemented some very basic optimization (as you show at the bottom of your post), but I'd imagine llvm is able to take things much further. I'd be curious to see a performance comparison.
I imagine it is because gcc -o is a convenient way to call the linker such that it correctly links the binary and libc. Doing this manually with ld would require several (non-portable) command line arguments that would be distracting from the main point of the post.
[0]: https://github.com/JoshMcguigan/nerve