Ohm's law is an empirical law that only holds in certain circumstances. A classic exercise is measuring the current and voltage across a lightbulb, plotting it, and measuring the slope of the line. The slope is the impedance. Then you turn up the voltage and watch the line turn into a curve, which is where the law breaks down and doesn't apply anymore. The engineers treat it like a definition and assume linearity over all voltage.
Disclaimer: I am physicist myself.