Depends how the encryption works - you only need to compute the cookie database key once.
Of course, regardless of what they do, you could probably just run a quick Frida (https://frida.re/) script to patch into Chrome and dump the key to disk when the decryption function is called.
From the 10 immutable laws of security:
Law #1: If a bad guy can persuade you to run his program on your computer, it's not solely your computer anymore.
Replayed later no, but a naive TOTP implementation will likely allow you to reuse an code more than once as long as you log in within the 30-second x N-lookback window.