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Not a spacecraft engineer, merely somebody who has studied physics a long time ago, so take my answer with a grain of salt.

Basically, there are two ways you can design a cooling system: one that involves phase change, and one that simply transports heat from A to B by moving a heat carrier, usually a liquid.

Phase change systems typically have a higher efficiency, because the phase change has larger relative energy than heat capacity. But it also has two disadvantages: it only works near the boiling point of the medium, and you need to deal with all the pressure changes that come with a phase change.

The Parker probe seems to use a "mere" transport, and there the heat capacity and the working range of the medium is very important, and water is a pretty good choice on both of these criteria.

Oh, and you also don't want something very corrosive to destroy your expensive space craft from the inside :-)

IIRC the ISS uses two cooling systems, one based on water that is used throughout the station, and then an ammonium-based system that takes the heat off the water and transports it to the heat radiators. But on the ISS, maintenance is possible.




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