Any advice for finding a job in that area? The HN "who's hiring" page doesn't have too much in NC, and other job sites seem to show mostly finance and consulting companies.
Depends on what you're looking for. Charlotte is 90% finance-related jobs (I used to work there myself). I live in the Raleigh/Durham area, and it has a decent amount of engineering opportunities, especially in biotech.
It's not the Bay Area, but it's pretty comfortable.
The tech startup scene is small, but very friendly and open. There's a few incubators. Check out meetup.com, it's pretty tech/startup heavy in Charlotte, see if there's something that catches your eye.