Yes, absolutely no problem. Did it this Sunday, and many others besides.
The only time I've had chafing issues was when doing a circle around the 'IJsselmeer' in one day. That was bad. But I was also peeing green and out for the count for the next day so enough time to heal up :)
Well, you've got my vote. I merely wanted to point out that an expensive outfit is not a requirement to starting out cycling and that you can do some pretty good rides without. If it works for you then that's great, and I'm happy to see you cycling, whatever you're wearing. The activity is what matters. If you ever make it to my neck of the woods consider yourself invited for a trip.