Nodejs out of the box would ofc. be faster than PHP on something nodejs is born to do. But lets say we needed to do a bit of CPU work on each of these requests, then nodejs might struggle compared to PHP.
Both should be able to scale well in a "create a website and return the HTML"-scenario, and it's not unlikely that a PHP setup would be faster.
In a single page app thats mostly based on fetching data from an API nodejs would probably be faster.
About APCu: It's damn fast and very unlikely to slow you down, other stuff will probably bottleneck you way before APCu becomes a problem.
Use PHP as PHP, and nodejs as nodejs.
If you really need async in PHP or want to use PHP somewhat like nodejs then you should probably go for an extension and serve requests directly from PHP. I've had great experiences with that, serving over 500K simple HTTP req/s on a low end server.
But again, if max performance on a single server is so important then you should probably go for a compiled language anyways.