If you haven't read it, I'd highly recommend the book, "The Alchemy of Air" about the invention of Haber-Bosch.. It was unbelievable what they went through to fix nitrogen, they literally invented new fields of study in materials science and chemistry. The perils of a Jewish inventor creating a new method for making explosives under the Third Reich is a side story in the book but another fascinating historical anecdote.
And also Zyklon which would become Zyklon B when the warning eye irritant was removed to make it a better weapon for murdering people. There was a RadioLab[1] episode that talked about how it was eventually used on some of his own relatives.
